Air Pollution Control Innovations

Wet Electrostatic Precipitators for Submicron Particulate Removal

Posted by Andy Bartocci on Mon, Apr 19, 2021 @ 08:30 AM

Industrial facilities are increasingly called upon to consider the use of wet electrostatic precipitators (WESPs) for emissions control as regulations for PM 2.5 and specific heavy metals become more stringent. Facility and Environmental, Health, and Safety (EHS) Managers may need to become familiar with WESP technology and how they can be applied to their facilities.

WESPs date back to the 1970’s and are a tried-and-true method for removing submicron particulates, aerosols, SO3, opacity, and condensed heavy metals. They are generally robust and suitable for 24/7 continuous operations. Their use is found in steel melting furnaces, secondary lead smelters, hazardous waste combustors (HWC), medical waste and sewage sludge incinerators, wood products and pellet manufacturing, mineral wool and glass manufacturing, silicon monomer manufacturing, semiconductor manufacturing, and even industrial fryers.

Particle Removal EfficiencyThe adjacent figure illustrates WESP’s primary use. The graph shows removal efficiency on the vertical axis and particle size on the horizontal axis. The red curve shows typical WESP performance.   The dotted blue curve shows typical Venturi scrubber performance. A comparison shows that a Venturi scrubber is highly effective at removing particles greater than 1 micron in size. However, performance drops off rapidly for particles below 1 micron. WESP performance is relatively immune to particle size and maintains high performance for particles below 1 micron. This capability is derived from the use of electrical forces for particle removal compared to a Venturi scrubber which uses mechanical forces. WESP’s are generally higher capital cost than Venturi scrubbers but lower operating cost. They are used in cases where performance cannot be achieved with a Venturi scrubber or other, lower cost control device.

Env wet scrubber arrangementWESPs are often integrated with other control technologies and used as a polishing device at the end of a process. This is shown in the adjacent illustration for a typical waste incinerator. Perhaps the most important aspect to understand about WESP technology is the relationship between performance, size, and cost. Higher performance requires more collection area, larger footprint, and more cost. This is different than other control technologies like a Venturi scrubber or packed bed scrubber. For these devices, size and cost is primarily determined by the gas flow rate while operating cost is determined by performance. Size and cost for a WESP on the other hand is determined not only by gas flow rate but also removal efficiency. It is therefore important to have a good understanding of the range of inlet particulate concentrations and outlet emission limits. Specifying performance of 90%, 95%, or 99% removal will make a substantial difference on size and cost.

WESP technologies can vary greatly between vendors which can have an impact on footprint, maintenance, and long-term performance. Some of these differences include:

  • Tube geometry (square, round, or hexagonal)WESP
  • Tube size
  • Tube length
  • Operating voltage
  • Electrode construction
  • Electrode alignment mechanism
  • Bottom support grid requirement
  • Gas distribution mechanism

It’s recommended that facilities evaluating WESP technologies dedicate time to understand differences in WESP designs and potential impacts on operations. Evaluation may also include how the WESP is integrated with other upstream equipment needed to meet multipollutant emissions criteria.

WESP technology is a substantial investment for any facility but may be the best available control technology for a submicron particulate application.

Click on the link below to download WESP scrubber literature.

Download Literature

Topics: particulate control, Scrubbers, wet electrostatic precipitators, SO3 Aerosol

Refinery Thermal Oxidizer SO2 scrubber and Sulfuric Acid Mist Candle Filter

Posted by Andy Bartocci on Wed, Apr 08, 2020 @ 10:00 AM

Sulfuric acid mist arrangementWaste oil is recycled and refined into low sulfur marine diesel and other industrial fuels at West Coast refineries. Waste gas is sent to thermal oxidizers for volatile organic compound (VOC) destruction. Sulfur compounds in the waste gas are oxidized to SO2 and removed by a packed bed scrubber. A fraction of SO2 converts to sulfur trioxide (SO3) before entering the scrubber. SO3 further converts to sulfuric acid (H2SO4) and generates a submicron liquid mist upon quenching the gas. New ground level pollutant regulations require removal of sulfuric acid mist before exhausting the flue gas to atmosphere. A multi-pollutant solution is needed to remove both SO2 and sulfuric acid mist. 

The customer selected an Envitech SO2 scrubber, candle filter system. The arrangement includes a quencher to cool the gas to saturation, a caustic packed bed absorber to remove SO2, and a candle filter to capture sulfuric acid mist. Internal ducts with outlets near grade simplifies ductwork between the caustic scrubber and candle filter and between the candle filter and ID fan. The scrubber comes with pre-assembled pump skids. Instruments are pre-mounted in pre-assembled piping and pre-wired to a junction box to reduce installation time and cost.

Both scrubbers have been shipped to the sites. The smaller system was put into service in early 2020. The scrubbers meet the design conditions summarized below.

candle filter

DESIGN PARAMETERS

Design Plant 1 Plant 2
Flow rate, acfm 10,000 4,500
Inlet temp, oF 1,600 376
SO2 removal > 90% > 95%
H2SO4 removal > 99% > 99%

 

 

 

 

 

 

Click on the link below to download a case study and related wet scrubber literature.

Download Literature

Topics: Scrubbers, SO2 Scrubber, Acid Gas, SO3 Aerosol, Packed Bed Absorbers, Packed Bed Scrubbers, Wet Scrubbers

International Conference on Thermal Treatment Technologies and Hazardous Waste Combustors (IT3/HWC)

Posted by Andy Bartocci on Mon, Aug 26, 2019 @ 10:55 AM

IT3 Logo

Envitech will be attending and exhibiting at the 37th International Conference on Thermal Treatment Technologies and Hazardous Waste Combustors (IT3/HWC) in League City, TX on October 2nd and 3rd, 2019. If you happen to be attending the conference, please stop by the Envitech booth or find me at the conference to say hello.

Three keynote panels will include high level experts and cover hot topics in the industry:

  • PFAS Overview, Regulatory Approach, Testing and Destruction
  • Emerging Air Quality Monitoring
  • Lessons Learned from the United Kingdom's 2018 Novichok Nerve Agent Incident

Papers presented in technical sessions cover:

  • Technologies and Trends in Incineration
  • Plastics Recycle and Reuse
  • Emission Monitoring
  • Waste-to-energy, Emission Monitoring, Pyrolysis 

Envitech will present papers on the following two topics.

Technology Solutions for Sulfuric Acid Formation and Removal in Liquid Waste and Waste Gas Thermal Oxidizers

Petrochemical plants, refineries, and waste-oil re-refiners operate liquid waste or waste gas thermal oxidizers.Candle filter The thermal oxidizers need a wet scrubber to neutralize and remove SO2. Flue gas entering the scrubber contain some sulfur trioxide (SO3) which is converted to sulfuric acid (H2SO4) in the quencher. Sulfuric acid is a submicron liquid aerosol that passes through the downstream packed bed absorber. Some facilities are now being regulated for H2SO4. This paper evaluates and compares candle filters versus wet electrostatic precipitators (WESP’s) for H2SO4 removal in these applications.

Sewage Sludge Incinerator (SSI) Mercury Control Technologies

Mercury Control ScrubberWaste water treatment facilities operating sewage sludge incinerators (SSI) can reduce sludge volume and disposal costs by combusting dewatered sewage sludge. Emissions are regulated by the US EPA Maximum Available Control Technology (MACT) standard 40 CFR Part 60 and 62 to control particulate, lead (Pb), cadmium (Cd), SO2, HCl, dioxins/furans, and mercury (Hg). Many SSI’s need a control device specifically for mercury. This paper evaluates two mercury control technologies: sulfur‐impregnated activated carbon and Gore sorbent polymer catalyst (SPC) modules. Several facilities have used sulfur-impregnated activated carbon but safety issues have arisen due to fires which have shut down some systems. The Gore SPC modules are a relatively new technology with at least seven installations. A comparison is made of capital cost, operating cost, mercury removal efficiency, fire and performance risks based on incineration of 3,000 lbs/hr of sewage sludge. Finally, an overview is provided for an Envitech SPC mercury control scrubber operating at one facility.

Click on the icon below to download an Envitech brochure.

Download Brochure

 

 

Topics: particulate control, Scrubbers, SO2 Scrubber, wet electrostatic precipitators, Acid Gas, Incinerator Scrubber, SO3 Aerosol

Technology Solutions for Sulfuric Acid Formation and Removal in Thermal Oxidizers

Posted by Andy Bartocci on Fri, Aug 23, 2019 @ 02:56 PM

Enivtech will be attending the 2019 International Conference on Thermal Treatment Technologies andCandle filter Hazardous Waste Combustors  (IT3/HWC)  October 2-3 in Houston, TX. A paper will be given on “Technology Solutions for Sulfuric Acid Formation and Removal in Liquid Waste and Waste Gas Thermal Oxidizers”. The paper is available for download by clicking the button at the bottom of this blog piece.

Petrochemical plants, refineries, and waste-oil re-refiners operate liquid waste or waste gas thermal oxidizers. The thermal oxidizers need a wet scrubber to neutralize and remove SO2. Flue gas entering the scrubber contains some sulfur trioxide (SO3) which is converted to sulfuric acid (H2SO4) in the presence of water vapor. Sulfuric acid is a submicron liquid aerosol that can pass through downstream equipment, such as a packed bed absorber or a baghouse. Some facilities are now being regulated for H2SO4.

WESPOver the last decade, Envitech has supplied SO2 scrubbers for thermal oxidizers burning sulfur containing compounds in refining applications. Most of these do not have add-on controls for capturing sulfuric acid mist. More recently, however, Envitech has supplied two systems with candle filters for the capture of sulfuric acid mist. Another known system used a wet electrostatic precipitator for the capture of sulfuric acid mist. A potential fourth system with a large gas flow rate with expected SO3 emissions was evaluated for a wet electrostatic precipitator.

A thermal oxidizer converts sulfur containing liquid or gaseous waste in the presence of excess oxygen to sulfur dioxide (SO2). A fraction of SO2 is further converted to SO3. The reaction is:

SO2 + 1/2O2 => SO3

The conversion amount is influenced by many factors including the thermal oxidizer operating temperature, residence time, sulfur concentration, amount of excess air, and the presence of catalytic oxides and metal catalysts in the fuel. Literature suggests that even a well-performing thermal oxidizer still converts 1 to 5% of SO2 into SO3. Given the numerous factors influencing the formation of SO3¬, most designers select a conservative estimate of SO3 conversion, even when actual SO3 emissions have been measured, as variations in operation can generate substantially higher conversion.

Once formed in the thermal oxidizer, SO3 reacts with water in the downstream quencher to form sulfuric acid (H2SO4) by the reaction:

SO3(g) + H2O(l) => H2SO4(l)

At temperatures below 350°F, H2SO4 condenses into submicron liquid droplets which are difficult to remove because of their small size. Aerosol droplets pass through a quencher and packed bed absorber. A separate control device is needed for sulfuric acid removal that is suitable for submicron droplets.

Click on the link below to download the IT3/HWC conference paper to learn about “Technology Solutions for Sulfuric Acid Formation and Removal in Liquid Waste and Waste Gas Thermal Oxidizers”. The paper evaluates and compares candle filters versus wet electrostatic precipitators (WESPs) for H2SO4 removal in these types of applications.

Download Literature

Topics: particulate control, Scrubbers, SO2 Scrubber, wet electrostatic precipitators, Acid Gas, Incinerator Scrubber, SO3 Aerosol