Air Pollution Control Innovations

There are several different waste incinerator source categories controlled by EPA standards under the Clean Air Act (CAA). These include hazardous waste combustors (HWC), sewage sludge incinerators (SSI), municipal solid waste (MSW) incinerators, commercial and industrial solid waste (CISWI) incinerators, and Hospital, Medical, and Infectious Waste Incinerators (HMIWI). Each incinerator type has its own Maximum Achievable Control Technology (MACT) standard which establishes technology based limits for emitted HAPs. MACT standards are part of the National Emission Standards for 

Hazardous Air Pollutants (NESHAP) and are applied to source categories that pose adverse risk to human health by the emission of hazardous air pollutants (HAPs).  The HMIWI MACT standard for medical waste incinerators is the most challenging of the incinerator source categories. This standard controls particulate (PM), hydrogen chloride (HCl), sulfur dioxide (SO2), lead (Pb), cadmium (Cd), mercury (Hg), dioxins/furans (D/F), nitrous oxide (NOx), and carbon monoxide (CO). Emission limits depend on the incinerator size and weather it is a new or existing source. Small incinerators are less than 200 lb/hr of waste throughput, medium incinerators are between 200 lb/hr and 500 lb/hr, and large incinerators are greater than 500 lb/hr.

Envitech recently completed a project for two medical waste incinerators at a Midwest research facility. These are the first new medical waste incinerators installed in the United States since Envitech installed a 525 lb/hr medical waste incinerator at a research facility in Galveston, TX in 2013.

The scope of supply includes two medical waste incinerator scrubbers and a water treatment system to treat the blowdown from both incinerators. The incinerators are permitted as new, medium size incinerators. Ozone injection is integrated into the system to meet a NOx limit of 67 ppmv. The systems include pre-assembled pumps, piping, valves, and fittings to minimize installation time and cost. The pre-assembly provides long term rigidity, consolidation of space, longer up-time, and improved safety for operators. A description of the process arrangement can be found in this link to an earlier blog post.

Stack testing was performed in June 2021 for both incinerators. Test results confirm the Envitech system reduced emissions well below MACT standard limits, providing a comfortable margin for compliance over the range of operating conditions and waste feed. Below is a summary of stack test performance.

Click on the link below to download literature on medical waste incinerator scrubbers.

A municipal waste water treatment plant operates a 2,750 lb/hr fluid bed sewage sludge incinerator (SSI). The incinerator had been shut down due to safety issues with the granulated activated carbon (GAC) mercury control scrubber. The plant sought expert help to evaluate and recommend a technology solution to replace the GAC and to get the SSI back in operation.

Based on extensive waste incineration gas cleaning experience, the facility contracted Envitech to evaluate the process, make recommendations, and implement a solution.

Envitech reviewed available literature and data to establish a conservative but justifiable design inlet concentration with sufficient capacity to meet a more conservative design condition without structural changes to the equipment.

An additional Envitech study compared W.L. Gore sorbent polymer catalyst (SPC) mercury control modules to sulfur impregnated activated carbon taking into account capital and operating cost, mercury removal efficiency, safety, and performance risk. The facility implemented Envitech’s recommendation for an Envitech SBC mercury control scrubber. A vessel constructed of fiber reinforced plastic (FRP) provides excellent corrosion resistance and low cost. An inlet heater duct with controls optimizes temperature for maximum performance. An internal duct with bottom outlet near grade direct connects to the existing stack. The vessel has extra capacity to double the number of SPC modules to meet the conservative inlet concentration if needed.

The equipment was commissioned in December, 2018. Inlet and outlet stack tests confirm greater than 96.4% removal and emissions less than 5% of the MACT limit for existing FB SSI. The Envitech SPC mercury control scrubber provides an economic, high performance, safe solution for continued incineration operation.  It can be applied to other types of applications that require mercury control downstream of wet scrubber equipment.  It provides a worthwhile technology to consider for mercury control.

Click on the link below to download a sewage sludge incinerator (SSI) mercury control scrubber case study and other SSI incinerator scrubbing literature.

Early this year I posted about achieving ultra-low emission limits for medical waste incinerator scrubbers.  An example was given for a captive incinerator at the University of Texas Medical Branch (UTMB) in Galveston, TX. It’s one of the only systems in the United States permitted as a “new” medical waste incinerator according to the EPA HMIWI (hospital, medical, and infectious waste incinerator) MACT standard. This standard has the most challenging emission limits found in industry today. That is because in 2009 the EPA completed a source review and revised the standard based on a MACT-on-MACT analysis.  Data used to set limits for each pollutant was individually based on waste feed and not incinerator/scrubber technology performance.  This resulted in emission limit reductions for lead (Pb), cadmium (Cd), and dioxins/furans (D/F) that were orders of magnitude below the previous standard and below the capability of installed equipment.  The impact of the new standard is discussed in greater detail in a 2013 blog post and corresponding paper from the Air & Waste Management Association (AWMA) International Conference on Thermal Treatment Technologies and Hazardous Waste Combustors (IT3/HWC)..
Existing incinerators needed to be upgraded with add-on controls to meet the new standard.  New incinerators need air pollution control equipment capable of extraordinarily high removal efficiency for particulate, Pb, Cd, and D/F.  A new medium sized incinerator between 200 to 500 lb/hr capacity, has the additional challenge of meeting NOx.  A medical waste incinerator can be tuned to a NOx limit of about 130 ppmv.  The MACT standard limit for a new medium sized medical waste incinerator was set at 67 ppmv which means NOx abatement is required to guarantee compliance.

Envitech is building two scrubber systems to treat exhaust gases from two new medical waste incinerators that will treat captive waste at a research facility.  The incinerators are permitted as new medium size incinerators which must meet the 67 ppmv NOx limit. The scrubbers have an equipment arrangement for meeting emission standards for PM, HCl, SO₂, Pb, Cd, Hg, D/F, and opacity.  The schematic below shows the components of the gas cleaning system. The quencher is used to cool the gas to saturation and remove large particulate. The packed bed condenser/absorber sub-cools the gas and removes acid gases with caustic injection. The Venturi scrubber removes particulate and the majority of heavy metals. The gas then passes through additional polishing controls to meet the ultra-low emission limits for Pd, Cd, Hg, and D/F. The polishing equipment includes a re-heat duct followed by a filter and carbon bed adsorber.

NOx removal is achieved by injecting ozone injection into the quencher outlet. The size of the condenser/absorber is increased to provide sufficient residence time for ozone-NOx reactions to occur.  Ozone is highly selective for NOx relative to other combustion products.   The NOx is rapidly converted to water soluble species. NO and O₃ react to form NO₂ and O₂.  NO₂ and O₂ react to form N₂O₅ and O₂. N₂O₅ and water react to form 2HNO₃ which is readily absorbed with caustic solution.

Envitech used it’s rectangular scrubber design for the condenser absorber. To maintain a modular design and make it shippable.  The vessel was flanged connected and shipped in two pieces. The scrubber system otherwise looks like a typical medical waste incinerator scrubber except the condenser/absorber is double the height compared to systems that do not require NOx control.

The system has been built and shipped to the site. The major components are installed at the facility.  Envitech will deliver a water treatment system in 2019 to treat the scrubber effluent before it is discharged to the facilities main water treatment system.  System Start-up is scheduled for 2020.

Click on the link below to download a case study and other medical waste incinerator scrubbing literature.

In 2009, the US EPA revised the emission limits for the Hospital, Medical, and Infectious Waste Incinerator (HMIWI) MACT standard. You can follow the link to the blog piece published in May 2013 on the new standard. It dramatically reduced the emission limits for several pollutants including particulate (PM), lead (Pb), and dioxins and furans (D/F). Several existing medical waste incinerators in operation at the time were not capable of meeting the new limits, especially for lead (Pb) and/or dioxin and furans (D/F). Cost effective add-on controls were needed to bring existing system into compliance with the new rules and to allow them to continue to operate.

To meet this new challenge, Envitech designed a carbon bed adsorber and filter package to be installed downstream of existing wet scrubbers. The package is comprised of a new fan to overcome additional system pressure drop. Heat of compression from the fan and a re-heater duct heats the wet gas above the dew point to prevent condensation fouling in downstream filter and/or carbon bed adsorber. The system is delivered pre-assembled on a skid to reduce installation time and cost. A cartridge filter removes low concentrations of condensed Pb particulate. The carbon bed adsorber removes dioxins, furans and mercury (Hg). Envitech has upgraded four medical waste incinerators to meet the new MACT standards. All four are operational and compliant with the new standards.

In one case for Wyoming Medical Center (WMC), space was limited for add-on controls. The system had to be installed outdoors and capable of withstanding below freezing temperatures. The existing system did not meet the new limits for lead (Pb) and dioxins/furnace (D/F).The add-on controls included a cartridge filter and a carbon bed adsorber. The equipment was insulated and heat traced to maintain temperature above the dew point after re-heat. System features include:

•  Shop and skid mounted assembly for ease of installation.
• Insulation and heat tracing for outdoor operation in a cold climate.
• Silicon controlled rectifier (SCR) controller to control the heater duct.
• Compressed air pulse cleaning for automatic particulate removal from the cartridge filters.
• Pre-wired instrumentation to a control box located on the skid.
• Manways to facilitate maintenance access.

The system has been operational since 2014 and has been used on a routine basis during cold winter months.   The system comfortably passed a stack test in 2015. Compliance for lead (Pd) is 20 times below the limit and Dioxins/Furans (D/F) is 5 times below the limit. The re-heat and filter package has been used on several other medical waste incinerators and provide a cost effective solution for meeting stringent emission limits. 

Download a free case study to find out how Wymoming Medical Center met the new EPA HMIWI emission limits for their existing medical waste incinerator.

Download a free white paper from the 2010 Internationa Conference on Thermal Treatment Technologies and Hazardous Waste Combustors (IT3/HWC) on the 2009 HMIWI MACT standard for medicl waste incinerators.

In October 2014, existing medical waste incinerators had to be compliant with the US EPA’s new Hospital, Medical, and Infectious Waste Incinerator (HMIWI) MACT standards. Nearly all of the systems that planned to continue incineratrion had to be upgraded with add-on controls to meet particulate (PM), lead (Pb), mercury (Hg), Cadmium (Cd), dioxins/furans (D/F), or a combination of the pollutants. Pb was the most common of those pollutants requiring additional capture.

Envitech upgraded scrubbers for three existing medical waste incinerators. In October 2015, I presented a paper at the International Conference of Thermal Treatment Technologies and Hazardous Waste Combustors (IT3/HWC) about using a wet electrostatic precipitator (WESP) on the National Institute of Health’s (NIH’s) Rocky Mountain Lab (RML) existing medical waste incinerator. Envitech also designed and built a fourth scrubber system which was permitted as a large (> 500 llb/hr of waste) new medical waste incinerator. The table below compares the previous 1997 standard for lead (Pb) for a large incinerator to the current (2009) standard for an existing incinerator and a new incinerator.

As shown, the current emission limit for an existing incinerator is just 3% of the limit for the 1997 standard. Add-on controls need to achieve 97% reduction in Pb for medical waste incinerators just meeting the previous limit. This is a significant reduction.

Lead (Pb) Emission Limits for Large Incinerators, mg/dscm

• 1997 standard                   1.2
• 2009 standard existing       0.036
• 2009 standard new            0.00069

Pb reduction for a new large medical waste incinerator is even more dramatic. The emission limit is a mere 0.06% of the 1997 standard. Compared to an existing system permitted to the new standard, a large new medical waste incinerator must emit 2 orders of magnitude less Pb.

Envitech’s scrubber for a permitted new medical waste incinerator recently passed the stack test and demonstrated compliance with Pb emission less than 0.00069 mg/dscm. We believe it’s the only systems in operation today that is compliant with the HMIWI MACT standard for a large, new medical waste incinerator.

It is interesting that despite the ultra low emission standards required by the HMIWI MACT standard, there is still significant public resistance to new permitted systems. It’s clear the public doesn’t understand the impact of these rules and how far technology has come to enable environmentally friendly and safe operation of these systems. The role of these captive systems (treating waste from the facility where it is generated) may become more important in emergency response plans of state and local governments. This was evident during the recent Ebola episode where large amounts of waste needed to be treated and disposed. Some would claim that treating the waste at the facility where it is generated poses less public risk than transporting the waste on public roads and highways to a centralized hazardous waste facility. More work needs to be done to educate the public on the capability of these advanced emission control technologies.

For more information on this topic, please read our paper at the IT3 conference.

Envitech will attend the International Conference on Thermal Treatment Technologies (IT3/HWC), October 20-22, 2015 at the Crowne Plaza Hotel in downtown, Houston, Texas.  The preliminary technical program can be downloaded from the conference website.   The conference features key note speakers from Veolia, Clean Harbors, Essroc, TCEQ, and B3 Systems.

Envitech will have an exhibit booth and present a paper, “Meeting the New Hospital, Medical, and Infectious Waste Incinerator (HMIWI) MACT with a Wet Electrostatic Precipitator (WESP)”.  The paper will provide an overview of a new medical waste incinerator scrubber system with a wet electrostatic precipitator to treat the off gas from two existing medical waste incinerators. The new system was required to achieve a 20% reduction in particulate (PM) emissions, and a 93% reduction in lead (Pb) emissions from the previous gas cleaning system.  The new system has been operational since October 2014.  The table below compares the performance of the emission limits to the new compliance standards. The results demonstrate the system comfortably meets the new EPA MACT standards.