Air Pollution Control Innovations

Andy Bartocci

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Ceramic Tile Kiln Acid Gas Scrubber: HF, HCl, SO2

Posted by Andy Bartocci on Thu, Oct 15, 2015 @ 01:38 PM

SO2 Scrubber Ceramic Tile Kiln

PROBLEM:

A Midwestern ceramic tile manufacturer needed an acid gas scrubber to treat the off gas from 3 kilns being installed at a new manufacturing plant. Each kiln was equal in size and emits HF, HCl, and SO2. The scrubber needed to remove > 98.5% of acid gases. The scope of supply included an ID Fan, interconnect duct, stack, control system, and pump skid. The facility was faced with the additional challenge of less than 22 ft of overhead space inside the building. A tight schedule required receipt of equipment in 16 weeks, including engineering. The customer operated other scrubbers at different facilities and reported difficulty in controlling the spray quenchers to cool and saturate the gas.

SOLUTION:

The customer selected an Envitech quencher/packed bed scrubber to meet their requirements. To eliminate difficulty in controlling gas cooling the scrubber used a proprietary, low pressure drop Venturi quencher. This provided a means to saturate the gas over a wide range of operating conditions and flow rates. The scrubber used a proprietary internal duct design with an outlet and entrainment separator at the bottom of the scrubber. This allowed the scrubber to fit in the low overhead space with no roof penetrations to minimize installation cost and time. Other equipment features included:

  •  Quencher design to capture > 90% of particulate > 3 microns.
  • Skid mounted dual pumps (1 opr/1 spare) with pre-piped and valved instruments.
  • Hydro-testing of piping assemblies.
  • Instruments pre-wired to a junction box.
  • Control System Factory Acceptance Test (FAT).
  • High efficiency, low pressure drop packing with high void spaces to prevent material accumulation and fouling.

 RESULTS:

The customer placed the order in June, 2015. The equipment shipped on time in October 2015 and arrived on site one week early, 15 weeks from order placement. The system will be operational in early 2016. Stack testing will confirm compliance with the performance guarantee summarized in the table below.

DESIGN

VALUE

Flow Rate, acfm

70,000

Inlet Temp, oF

482

HF Removal

> 98.5%

HCl Removal

> 97%

SO2 Removal

> 53%

 To download a Free Case Study, please click on the icon below.

Download  Case Study

 

 

 

Topics: Scrubbers, SO2 Scrubber, Acid Gas, quenchers

IT3/HWC 2015 Conference October 20-22, 2015 – Wet Electrostatic Precipitator for Medical Waste Incinerators

Posted by Andy Bartocci on Tue, Sep 22, 2015 @ 10:47 AM

Envitech will attend the International Conference on Thermal Treatment Technologies (IT3/HWC), October 20-22, 2015 at the Crowne Plaza Hotel in downtown, Houston, Texas.  The preliminary technical program can be downloaded from the conference website.   The conference features key note speakers from Veolia, Clean Harbors, Essroc, TCEQ, and B3 Systems.

Envitech will have an exhibit booth and present a paper, “Meeting the New Hospital, Medical, and Infectious Waste Incinerator (HMIWI) MACT with a Wet Electrostatic Precipitator (WESP)”.  The paper will provide an overview of a new medical waste incinerator scrubber system with a wet electrostatic precipitator to treat the off gas from two existing medical waste incinerators. The new system was required to achieve a 20% reduction in particulate (PM) emissions, and a 93% reduction in lead (Pb) emissions from the previous gas cleaning system.  The new system has been operational since October 2014.  The table below compares the performance of the emission limits to the new compliance standards. The results demonstrate the system comfortably meets the new EPA MACT standards.

 

Pollutant

 

Units

Compliance

Limit

Test Result

% of limit

Particulates, EPA Method 5 gr/dscf 0.020 15%
Pb EPA Method 29 mg/dscm 0.018 6%
Cd, EPA Method 29 mg/dscm 0.013 10%
Hg mg/dscm 0.025 1.0%
Dioxins/furans, EPA Method 23 Total (ng/dscm) 0.85 5%
  TEQ (ng/dscm) 0.020 15%
HCl, EPA Method 26 ppmv 7.7 1.6%
SO2 ppmv 4.2 35%

Click on the icon below to download a copy of the paper.

Free_Paper

Topics: particulate control, Venturi scrubbers, wet electrostatic precipitators, MACT Standards, Medical Waste Incinerator Scrubber, Incinerator Scrubber, HMIWI Scrubber

Rectangular Acid Gas Scrubber Lowers Installation Cost and Improves Maintenance

Posted by Andy Bartocci on Thu, Jul 09, 2015 @ 12:29 PM

Acid gas scrubbers are one of the most common types of air pollution control systems found in industry.  They are often used to treat exhaust gases from combustion sources such as incinerators, hazardous waste combustors, thermal oxidizers, regenerative thermal oxidizers (RTO), furnaces, and direct fired heaters.   Acid gas scrubbers are found on a wide range of facilities including, geothermal plants, secondary lead smelters, waste oil re-refiners, refineries, chemical and pharmaceutical plants, and mineral and metal processing facilities.  The most common types of acid gas emissions are HCl and SO2, but can also include Cl2, HBr, HF, and NOx.

Most acid gas scrubbers are wet scrubbers using vertical packed bed absorbers.   In the case of combustion sources, the scrubber is coupled to an evaporative quencher to cool the gas to saturation before it passes to the packed bed. This arrangement is shown in the adjacent figure for a medical waste WSU_Vertical_Scrubberincinerator.  The incinerator exhaust is ducted to a metal quencher (shown in the foreground). The hot gas enters the top of the quencher and flows vertically downward. The gas then elbows into the bottom of a vertical packed bed scrubber (shown in the background). The gas passes upward through the packed bed as re-circulated water flows downward, counter-current to the gas from the top of the packed bed.  Water from the quencher and packed bed is collected in the sump and re-circulated back to the quencher and packed bed.  An entrainment separator at the top of the scrubber removes entrained water droplets.  After exiting the scrubber vessel, an interconnect duct transports the gas to a induced draft fan located at grade.

The scrubber above is one of the earliest Envitech medical waste incinerator scrubbers.  These types of scrubbers are often installed in hospitals where critical design considerations include limited space, low ceilings, and difficult to reach locations through elevators and narrow corridors.  To help minimize installation costs Envitech developed a rectangular scrubber which is shown in the figure below. 

UTMB_Scrubber_Skid_Pic

 

 

 

 

 

 

 

 

 

 

 

This configuration provides several advantages over a vertical scrubber, including:

Greater integration and pre-assembly of ancillary equipment and pumps, piping, valves, and fittings.

  • Ground level access manways for safer, easier maintenance.
  • Simplified ductwork connection to the fan and stack.
  • Elimination of caged ladders and platforms for nozzle and mist eliminator access.
  • Ability to fit in locations with low head space.
  • Simplified requirements for setting and integrating equipment which lowers installation costs.

The rectangular scrubber has been used on over 60 installations.  Envitech has found that facilities tend to prefer a rectangular design over a vertical scrubber for the advantages noted above.  In some cases, total installed cost is reduced by 40% to  50%.  Weather a scrubber is purchased from an EPC contractor, upstream equipment supplier, or architectural & engineering firm, it is recommended that facility preferences be taken into consideration in the final selection process.

The video link below shows a few recently installed rectangular scrubbers at waste oil re-refiners as well as several examples of other rectangular scrubber installations.

 

 

Click the link below for a free case study on  a rectangular acid gas scrubber for a direct fired heater at a waste oil re-refiner.

Download Case Study

Click the link below for a free case study on a rectangular medical waste incinerator scrubber for the control of acid gases, particulate, and heavy metals.

Download Case Study

Topics: Scrubbers, SO2 Scrubber, Acid Gas, HMIWI Scrubber

Refinery Sulfur Recovery Unit (SRU) SO2 Scrubber for Startup, Shutdown, and Malfunctions

Posted by Andy Bartocci on Wed, Jun 24, 2015 @ 02:55 PM

For years, many states have exempted industrial facilities from rules prohibiting the release of toxic pollution during startup, shutdown, and malfunctions. That could all soon change.  On May 22, 2015, the U.S. Environmental Protection Agency (EPA) finalized a rule which will force state regulators to limit industrial upset emissions. The EPA issued a state implementation plan (SIP) call action to 36 states directing them to correct specific startup, shutdown, and malfunction provisions in their SIPs to ensure they are fully consistent with the Clean Air Act (CAA).  The ruling will affect a wide range of facilities including refineries, chemical manufacturers, and natural gas producers.  This will create challenges for state regulators and industrial facilities and opportunities for technology providers and environmental consulting and engineering firms.
A common industrial application which may be impacted by the new rule is found in refineries for sulfur recovery units (SRU).  Most SRU’s are based on a multi-step Claus process which recovers sulfur from gaseous hydrogen sulfide. The hydrogen sulfide is found in by-product gases from refining crude oil and other industrial processes.  A Tail Gas Treatment Unit (TGTU) follows the SRU to recover sulfur and return it to the SRU.  A TGTU can yield 99.9% sulfur recovery for a typical oil refining plant.  An inRefinery SO2 Scrubbercinerator and waste heat boiler treats the TGTU off-gas before it is exhausted to atmosphere. During normal operations, there is very little SO2 emissions due to the high sulfur recovery. However, TGTU upsets can occur several times per year which sends unrecovered sulfur to the incinerator.  During these upsets, SO2 emissions can be as high as 1 tph  or more for a period of 8 to 12 hours.Envtech is designing a refinery standby SRU tail gas caustic scrubber which will eliminate SO2 emissions during upset conditions.  The scrubber uses Envitech’s proprietary quencher which acts as a low pressure drop Venturi. The quencher is  followed by a packed bed absorber for SO2 removal.  The overall pressure drop is less than 10 inches and has lower power consumption than other types of SRU scrubbers installed in refineries.   Special design considerations enable the exhaust gas to pass through the scrubber at both elevated and cool temperatures.  During normal operation, hot gas from the TGTU passes through the scrubber in standby mode with the re-circulation pumps turned off.  In this mode, the gas is at elevated temperatures of 500oF to 600oF.  During a trip event, the TGTU is bypassed and the recirculation pumps turn on automatically.  The gases are then cooled to saturation and SO2 is absorbed and removed in the packed bed.  Implementation will enable the facility to reduce SO2 emission by 40 to 80 tpy and to meet the new EPA compliance standards for start-up, shutdown, & malfunction.    The scrubber is a good example of how an innovative solution can help a facility meet the new emission requirements during upset conditions with significant benefit to the environment.

 

To read more about the use of Envitech's scrubbers in difficult refinery applications, please download the white paper below on the topic of meeting ultra-low SO2 emissions.

Download Paper

Topics: Scrubbers, SO2 Scrubber, Acid Gas

Medical Waste Incinerator Scrubber Used to Process Ebola Waste

Posted by Andy Bartocci on Wed, Nov 05, 2014 @ 05:43 PM

Envitech recently got noticed in a local news story by Michael Chen of Channel 10 News, “Local Company Helps Dispose of Ebola-tainted Waste”.  The story talks about the challenges of processing Ebola waste and how Envitech’s Medical Waste Incinerator Scrubber at the University of Texas Medical Branch (UTMB) was used to dispose of waste generated by an Ebola patient in Texas.

UTMB operates the only permitted medical waste incinerator in the state of Texas.  Since 1991 the facility has operated an incinerator which uses an Envitech wet scrubber system to clean the exhaust gases of harmful pollutants.  A new incinerator system was recently installed to meet the new EPA rules promulgated for the hospital, medical, and infectious waste incinerator (HMIWI) maximum achievable control technology (MACT) standard.  The impact of these rules is discussed in a previous blog post.

The outlet emission requirements of the new standards are a significant reduction from the previous 1997 standards.  The allowable outlet emissions for many of the metals, i.e. lead (Pd), Cadmium (Cd) are less than 1% of the previous emission limits. For example, the allowable concentrations for Pb,and Cd are measured in 10-7 and 10-8 gr/dscf, respectively.  These are some of the lowest HAPs emission limits for industrial sources in the United States. Medical Waste Scrubber Below is a summary performance guarantee for the new scrubber system based on the new HMIWI standard:

  • PM < 18.3 mg/dscm (0.008 gr/dscf)
  • Lead < 0.00069 mg/dscm (3.0 x 10-7 gr/dscf)
  • Cd < 0.00013 mg/dscm (5.7 x 10-8 gr/dscf)
  • HCl < 5.1 ppmv dry
  • SO2 < 8.1 ppmv dry
  • Dioxins/Furans < 0.035 ng/dscm on TEQ basis

Recent episodes of processing highly infectious waste from Ebola patients may re-ignite a policy debate on medical waste disposal. In the early 1990, many hospitals were going to a model of owning and operating a relatively small medical waste incinerator to process and destroy medical waste generated in-house. These systems typically have a capacity of 500 to 1,500 lb/hr. As air emission standards became stricter, many hospitals decided to shut down their incinerators and ship their waste to larger, centralized medical waste incinerators. These systems are much larger in capacity. For example, the largest medical waste incinerator facility is in Baltimore, MD with a permitted capacity of 150 ton/hr. The trade-off of a centralized waste incinerator is the risk and liability of transporting the waste on public roads and highways. The recent Ebola outbreaks bring to light that some of this waste can be highly infectious and pose a significantly greater risk to public health. It also came to light that a single Ebola patient generates a substantial amount of infectious waste. In this scenario, it may make more sense for facilities to have the capacity to destroy their own waste and avoid the risk of transporting it over great distances on public roads.

The advancement of scrubber technology and compliance with the new, more stringent EPA MACT standards, confirm the ability to operate medical waste incinerators with virtually no harmful emissions into the air.  In addition to the UTMB medical waste scrubber system, Envitech has upgraded several other medical waste incinerators for meeting the new standards.  Based on the extreme low emission limits, the results are truly groundbreaking and may encourage states and facilities to permit new systems.

For more information on HMIWI regulations, please read our white paper.

Download Free Paper

Topics: Venturi scrubbers, MACT Standards, Ebola Waste, Medical Waste Incinerator Scrubber, Incinerator Scrubber, HMIWI Scrubber

Marine Diesel Scrubber Passes CARB Testing

Posted by Andy Bartocci on Mon, Jan 13, 2014 @ 04:04 PM

Marine ScrubberIn 2012 Envitech designed and built a marine diesel scrubber to remove SO2 from the engine exhaust of ocean going vessels.  The scrubber was integrated into the Advanced Maritime Emissions Control System (AMECS) used at the Port of Long Beach.  AMECS is a stationary system that uses a bonnet to capture the exhaust gas from the ships stack while at port. The exhaust gases are conveyed to AMECS to clean the gases of particulate (PM), NOx and SOx before exhausting to atmosphere. This allows the ship to operate its auxiliary engines and boiler system while at port to provide power to the ship.  AMECS provides a cost effective way for ships and port operators to reduce emissions and to meet tougher regulatory standards. 

The AMECS team recently announced that the California Air Resource Board (CARB) has approved AMECS as an alternative technology for the At-Berth Regulation.  This approval follows more than 1500 hours of validation testing on 40+ vessels during 2012 and 2013.  The most recent testing occurred in October of 2013 and was attended by representative of CARB and SCAQMD as well as representatives from the Ports of Long Beach and Los Angeles.  The test yielded impressive results, including:

    • PM                                                                  94.5%
    • NOx (@1.6ppm ammonia slip)                       99+%
    • SO2                                                                 98.5%
    • VOCs                                                              99.5%

In a parallel track, the maritime industry is looking for ways to meet tougher standards not only at port but while operating at sea based on the IMO Annex VI MARIPOL Tier III requirements. Envitech continues to develop De-SOx technology options for ship based marine diesel engines.  The recent CARB approval is a milestone achievement for demonstrating the Envitech scrubbers ability to achieve high SO2 removal efficiency over a wide range of diesel exhaust and operating conditions.

Click on the link below to download a case study on the marine scrubber.

Download  Case Study

Topics: Scrubbers, SO2 Scrubber, Marine Scrubber

Arsenic Scrubber for Copper Mine Roaster

Posted by Andy Bartocci on Thu, Jan 09, 2014 @ 01:00 PM

With an expanding global population, demand for minerals continues to grow.   Development of non-traditional resources is expected to increase to meet this growing demand. This includesCopper Mine copper resources challenged by high levels of arsenic.  Mining operations may incur penalties for arsenic in concentrates that exceed a certain amount.  As ore with low levels of arsenic is depleted, these penalties will continue to rise.

One facility seeking to reduce the impact of penalties is the Aranzazu project in Zacatecas Mexico by Aura Minerals.  The facility will use a partial roasting technology by Technip to achieve arsenic reduction in the concentrate.  After treatment, the concentrate is expected to contain less than 0.3% arsenic.  This will decrease expected arsenic related penalties by up to $1.00 per payable pound of copper produced.

wet electrostatic precipitator

 

The roaster off-gas will be treated by an Envitech wet scrubber system to remove arsenic with a 99.9% performance guarantee. The inlet gas to the scrubber will be at an elevated temperature well above 1,000oF and will have a high concentration of particulate, sulfur, and arsenic. The scrubber system combines Envitech’s wet scrubber technology which has been used to remove hazardous air pollutants from medical and hazardous waste incinerators with Envitech’s wet electrostatic precipitator technology (WESP) for final collection and removal of arsenic.  Envitech’s WESP technology has demonstrated high performance for arsenic removal on other furnace applications at secondary lead smelting facilities.

 For more information on the removal of heavy metals using wet electrostatic precipatators, please download our white paper on the capture of emissions from a smelter.

Download Free White Paper

 

Topics: Venturi scrubbers, wet electrostatic precipitators

Geothermal Plant SO2 Scrubber

Posted by Andy Bartocci on Fri, Sep 13, 2013 @ 08:56 AM

A geothermal plant produces a sustainable source of energy by converting super heated fluidsGeothermal Plant SO2 scrubber from the earth’s geothermal resources into electrical energy.  The fluids are recovered in the
process and re-injected back into the earth. The following YouTube video from CalEnergy provides a good overview of how a typical geothermal plant works.  California currently obtains about 4.5% of its electricity from geothermal plants. Most of these plants are sized at 50 MW but some plants can be larger in the 150MW range.  There is an estimated 2,300 megawatts of undeveloped energy in an area in Imperial County California near the Salton Sea just outside of San Diego.

SO2 Scrubber Geothermal Plant

 

The geothermal energy conversion process generates a sulfur containing off-gas which passes through a thermal oxidizer to destroy volatile organic compounds (VOC’s).   The sulfur compounds are oxidized to sulfur dioxide (SO2) and must be removed before exhausting to atmosphere.  A packed bed absorber treats the thermal oxidizer exhaust to remove SO2.  Often times geothermal plants are located in an extreme desert environment with summer  temperatures reaching > 120oF.  The scrubber equipment must be designed to achieve high removal efficiency, continuous operation and withstand the extreme environment.    

 

Click the link below to download a case study for an SO2 scrubber installed at an ORMAT geothermal plant near the Salton Sea in Southern California.

Download  Case Study

Topics: Scrubbers, SO2 Scrubber, Acid Gas

Sulfite Pulp Mill SO2 Scrubber and Wet Electrostatic Precipitator

Posted by Andy Bartocci on Mon, Jul 15, 2013 @ 03:57 PM

 A previous blog post made a case study available for wet electrostatic precipitator (WESP), SO2 scrubber system that will treat the off-gas of a red liquor recoverywesp boiler for a sulfite pulp mill in Quebec, Canada.  The scrubber system is part of a larger green energy project that will produce 40-megawatts of power and increase annual production capacity of specialty cellulose by 5,000 metric tonnes.   The new production capacity is slated to be complete by September 2014.

The system is comprised of a sulfur recovery island that cools the boiler exhaust gases and recovers sulfur using ammonia as a scrubbing reagent.  SO2 ScrubberThe sulfur containing effluent is re-used in the cellulose producton process. The sulfur recovery island is followed by a gas cleaning island comprised of an packed bed SO2 scrubber integrated with an Envitech wet electrostatic precipitator (WESP).  The gas cleaning island removes SO2 and particulate before exhausting to the atmosphere.

Envitech has completed the system design and released major equipment orders. Some major components will be complete as early as this month.  Delivery will take place before the end of 2013. The adjacent and  above images show a recent rendering of the system.

UPDATE: See the case study for this system by clicking on the link.

Download  Case Study 

 

 

 

 

 

Wet Scrubber Technology for Reducing China’s Air Pollution

Posted by Andy Bartocci on Wed, Jun 26, 2013 @ 12:01 PM

Envitech recently got noticed in a local news story by Michael Chen of KGTV Channel 10 News, “San Diego Companies Could Help Clean China’s Air”.  The story is about how California’s Governor Jerry Brown’s diplomatic trip to China could lead to opportunities for local San Diego companies like Envitech.  During his visit, Gov. Brown signed a pact that will pave the way for California companies to help China measure and improve its air quality.   As a leader in industrial air pollution control equipment, Envitech has process technology that can be used in China for reducing hazardous air pollutants (HAPs) and pollutants that contribute to regional haze like sulfur dioxide (SO2). These technologies have been applied to many processes in North America including a coal gasification plant, hazardous waste incinerators, lead smelters, sulfite pulping mills, waste oil re-refiners, geothermal plants, and mining and mineral processing to name a few.  Envitech has pursued several opportunities in China through 3rd party customers and will have one installation starting up later this year.

For more information on Envitech's capabilities, please download our product brochure.

Download Brochure

Topics: particulate control, Venturi scrubbers, gasification, Scrubbers, SO2 Scrubber, wet electrostatic precipitators, cleaning systems